11.1 Introduction Rubber is an elastic material and it is often called an ‘elastomer’. It also possesses a viscous nature, which is manifested in temperature-rises during mixing, i.e., viscous energy dissipation. Although its viscoelastic nature has been recognised for some time, the discussion on mixing of rubber often ignores viscoelasticity. One reason for this may lie in the fact that many people are unfamiliar with viscoelasticity. Another reason may be that methods for applying viscoelasticity to practical situations are not adequately developed. The latter concerns the handling of non-linear viscoelasticity in particular. It also includes fracture behaviour of rubber. This chapter will discuss the mechanisms of mixing fillers with gum rubbers. It is primarily concerned with the use of internal mixers. 11.2 Problems associated with internal mixers In discussing problems associated with internal mixers, we begin with the differences in operation between the mill and the internal mixer. In the mill operation, it is possible to observe what is happening, whereas with internal mixers, direct observation is not possible. In mill mixing, the operator participates in the production process by adjusting mill gap, cutting and rolling rubber sheet, and recharging. The repeated take-off and recharging are to give a uniform treatment of the compound. With internal mixers, the gap between the rotor wing and the chamber wall corresponds to the mill gap. However, the contents of the mixer do not necessarily pass the gap uniformly; some parts may go through more times than other parts. Some parts may even remain stagnant. In general, the history of deformation and fracture of rubber during mixing is non-uniform. The degree of nonuniformity depends on the rotor configuration and on whether the rotors are intermeshing or non-intermeshing. In addition, the viscoelasticity of a given gum rubber has a decisive influence on the uniformity. The uniformity in this discussion primarily concerns the macroscopic differences but it is indirectly related to microscopic inhomogeneity also. The fill factor most suitable for the mixing of rubber is about 70-75%, which was determined through experience. In order for the mixer’s contents to move uniformly, a
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