lec.3

The Iron-Carbon Diagram
There are two iron-carbon equilibrium diagrams:
- stable iron-graphite Fe-Gr
- metastable iron-cementite Fe-Fe3C
The stable condition usually takes a very long time to develop. The metastable diagram is of more interest. Fe3C iron carbide called cementite because it is hard.
Following phases exist on Fe-Fe3C diagram:
- liquid solution of iron and carbon (L)
- ferrite (?) – an interstitial solid solution of carbon in Fe? (bcc). At room temperature ferrite is ductile but not very strong.
- austenite - an interstitial solid solution of carbon in Fe? (fcc).
- cementite (Fe3C) hard and brittle compound with chemical formula Fe3C. It has metallic properties.
On a base of Fe-Fe3C diagram we can divide iron-carbon alloys into:
- steels,
- cast steels,
- cast irons.
Steel is an alloy of carbon and iron and other alloying elements (e.g. Mn, Si) with carbon content up to 2% intended for wrought products or semi products.
Cast iron is an alloy of carbon and iron and other alloying elements (e.g. Mn, Si) with carbon content over 2% intended for castings.
Now, we consider only a part of Fe-Fe3C diagram referring to steel.
Perlite is a structure (i.e. consists of two phases) consists of alternate layers of ferrite and cementite in the proportion 87:13 by weight. Perlite is formed from austenite at eutectoid temperature (A1) 727°C upon slow cooling.
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