Why Study Applications and Processing of Ceramics? It is important for the engineer to realize how the applications and processing of ceramic materials are influenced by their mechanical and thermal properties, such as hardness, brittleness, and high melting temperatures. For example, ceramic pieces normally cannot be fabricated using conventional metal forming techniques. They are often formed using powder compaction methods, and subsequently fired (i.e., heat treated). Fabrication and Processing of Ceramics: ceramic materials have relatively high melting temperatures, casting them is normally impractical. Furthermore, in most instances the brittleness of these materials precludes deformation. Some ceramic pieces are formed from powders (or particulate collections) that must ultimately be dried and fired. Glass shapes are formed at elevated temperatures from a fluid mass that becomes very viscous upon cooling. Cements are shaped by placing into forms a fluid paste that hardens and assumes a permanent set by virtue of chemical reactions. A taxonomical scheme for the several types of ceramic-forming techniques is presented in Figure 1. Glass Properties: Glassy, or noncrystalline, materials do not solidify in the same sense as do those that are crystalline. Upon cooling, a glass becomes more and more viscous in a continuous manner with decreasing temperature; there is no definite temperature at which the liquid transforms to a solid as with crystalline materials. In fact, one of the distinctions between crystalline and noncrystalline materials lies in the dependence of specific volume (or volume per unit mass, the reciprocal of density) on temperature. Also important in glass-forming operations are the viscosity–temperature characteristics of the glass. Figure 2 plots the logarithm of viscosity versus the temperature for fused silica, high silica, borosilicate, and soda–lime glasses. On the viscosity scale several specific points that are important in the fabrication and processing of glasses are labeled:
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